For all I know everything i've encountered is little endian - which is pretty logic as it comes from a Windows game. I see 'endianness?' Mentioned somewhere in the document. Is that document something you found somewhere, or something you're writing yourself as a kind of manual? That's great! Really glad that I inspired you and I think your knowledge and experience from the DLL-stuff will come in handy when decoding the entire savegame.
It overalls the traffic system, adds a lot of new roads/freeways and makes a huge change and a much better change to the game. You will be amazed by what the mods do to make a much better game! NAM (Network Addon Mod) especially is a 100% required mod. I highly recommend checking those mods out. SimMars is a mod for SimCity 4 taking the game to Mars. The Network Addon Mod, or NAM, is a modification for SimCity 4 Deluxe, which adds a myriad of new transport network items, ranging from ground light rail, to fractional-angle roads, to roundabouts, and much more.